The ZSOM-Control and the ZSOM-Mini each provide one RS232 interface. It is based on a serial port of the sbRIO-9651 and an RS232 transceiver.
The interface is a serial port of NI Linux Real-Time and is used from RT code with the NI-VISA serial functions (VISA Configure Serial Port, VISA Write, VISA Read).
See the examples included in the SDK: